Figure 1.
(ADPr: ADP-ribosylated/ADP-ribosylation; NAM: Nicotinamide; Ⓟ: phosphate; PR: phosphoribosyl; SN1: Nucleophilic Substitution, First Order — reaction mechanism for catalysing ADP-ribosylation which involves an oxocarbenium ion generated by NAD+ cleavage for nucleophilic attack of acceptors; * anomeric carbon linking ADP-ribose to acceptors).
Overview of non-canonical ADP-ribosylation reactions discussed in this review.

(ADPr: ADP-ribosylated/ADP-ribosylation; NAM: Nicotinamide; Ⓟ: phosphate; PR: phosphoribosyl; SN1: Nucleophilic Substitution, First Order — reaction mechanism for catalysing ADP-ribosylation which involves an oxocarbenium ion generated by NAD+ cleavage for nucleophilic attack of acceptors; * anomeric carbon linking ADP-ribose to acceptors).

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