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Keywords: electron transfer
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Articles
Biochem Soc Trans (2023) 51 (4): 1611–1619.
Published: 06 July 2023
...Wataru Sato; Koichiro Ishimori In mitochondria, electrons are transferred along a series of enzymes and electron carriers that are referred to as the respiratory chain, leading to the synthesis of cellular ATP. The series of the interprotein electron transfer (ET) reactions is terminated...
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Biochem Soc Trans (2013) 41 (5): 1305–1311.
Published: 23 September 2013
... © 2013 The Authors 2013 di-iron carboxylate protein electron transfer protein engineering respiration ubiquinol oxidase It is generally recognized that the distribution of the AOX (alternative oxidase) is substantially wider than previously thought [ 1 ]. In addition to being...
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Biochem Soc Trans (2012) 40 (6): 1308–1314.
Published: 21 November 2012
...Amit Kumar; Krishna Katuri; Piet Lens; Dónal Leech Electrochemical gradients are the backbone of basic cellular functions, including chemo-osmotic transport and ATP synthesis. Microbial growth, terminal respiratory proteins and external electron transfer are major pathways competing for electrons...
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Biochem Soc Trans (2012) 40 (6): 1268–1273.
Published: 21 November 2012
... transfer includes the decahaem cytochrome DmsE, a paralogue of the MtrA family of decahaem cytochromes. Although both DmsE and MtrA are decahaem cytochromes implicated in the long-range electron transfer across a ~300 Å (1 Å=0.1 nm) wide periplasmic ‘gap’, MtrA has been shown to be only 105 Å in maximal...
Includes: Supplementary data
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Biochem Soc Trans (2012) 40 (6): 1315–1318.
Published: 21 November 2012
...Haluk Beyenal; Jerome T. Babauta The chemical and electrochemical gradients in biofilms play a critical role in electron-transfer processes between cells and a solid electron acceptor. Most of the time, electron-transfer processes have been investigated in the bulk phase, for a biofilm electrode...
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Biochem Soc Trans (2012) 40 (6): 1178–1180.
Published: 21 November 2012
... respiratory pathway. The structure of MtrF, a paralogue of MtrC in S. oneidensis , has provided insight into electron-transfer reactions beyond the OM [ 8 ], and a low-resolution solution-based structure of MtrA has been described [ 9 ]. The MtrA structure indicates that this protein is approximately 10 nm...
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Biochem Soc Trans (2012) 40 (6): 1163–1166.
Published: 21 November 2012
... they are insoluble in water, they cannot enter the bacterial cells. So, to exploit these electron sinks and sources, specific respiratory electron-transfer mechanisms must overcome the physical limitations associated with electron transfer between a microbe and extracellular metal oxides. Recent microbiological...
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Biochem Soc Trans (2012) 40 (3): 493–500.
Published: 22 May 2012
.... These extracellular proteins are charged with electrons provided by an inter-membrane electron-transfer pathway that links the extracellular face of the outer membrane with the inner cytoplasmic membrane and thereby intracellular electron sources. In the present paper, we consider the common structural features...
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Biochem Soc Trans (2011) 39 (6): 1895–1899.
Published: 21 November 2011
... and orientation of the globular domains by these tethers favours the formation of electron-transfer complexes for entropic reasons. The attachment to the outer membrane may also affect the exposure of the host to redox proteins with a moonlighting function in the host–microbe interaction, thus affecting the host...
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Biochem Soc Trans (2009) 37 (2): 400–407.
Published: 20 March 2009
... subjected to an intensive spectroscopic scrutiny, coupled with genetic manipulation and structural studies, that has revealed many of the molecular and mechanistic details of biological energy transfer, electron transfer and coupled proton translocation. This review provides a short overview...
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Biochem Soc Trans (2009) 37 (2): 413–418.
Published: 20 March 2009
...-[aziridin-1-yl]-2,4-dinitrobenzamide (CB1954) cancer treatment electron transfer Escherichia coli nitroreductase hydride transfer virus-directed enzyme prodrug therapy (VDEPT) VDEPT (virus-directed enzyme prodrug therapy) is a gene therapy approach to cancer treatment aimed at overcoming...
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Biochem Soc Trans (2009) 37 (2): 392–399.
Published: 20 March 2009
... Biochemical Society 2009 electron transfer haem-copper oxidase membrane protein nitric oxide nitrous oxide proton transfer The volume of nitrous oxide (N 2 O) discharged into the atmosphere each year is lower compared with carbon dioxide (CO 2 ) and methane. However, because it persists...
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Biochem Soc Trans (2008) 36 (6): 1169–1174.
Published: 19 November 2008
... and, in addition, it is also linked to proton pumping across the membrane. Thus the Cyt c O moves an equivalent of two positive charges across the membrane per electron transferred to O 2 . Proton transfer through Cyt c O must be controlled by the protein to prevent leaks, which would dissipate the proton...
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Biochem Soc Trans (2006) 34 (6): 1173–1177.
Published: 25 October 2006
... arrangement enables efficient electron transfer within the enzyme and a catalytic efficiency that cannot be matched in P450 systems from higher organisms. P450 BM3's potential for industrially relevant chemical transformations is now recognized, and variants with biotechnological applications have been...
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Biochem Soc Trans (2006) 34 (1): 188–190.
Published: 20 January 2006
... NOR and the chemically less reactive oxidant O 2 [Flock, Watmough and Ädelroth (2005) Biochemistry 44 , 10711–10719]. When fully reduced NOR reacts with O 2 , proton-coupled electron transfer occurs in a reaction that is rate-limited by internal proton transfer from a group with a p K a of 6.6...
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Biochem Soc Trans (2005) 33 (4): 825–828.
Published: 01 August 2005
... thermodynamics relationships in systems biology. The future lies with the second as the first is nearing completion. © 2005 The Biochemical Society 2005 bioenergetics of evolution chemical elements in evolution electron transfer laws of thermodynamics molecular machines proton transfer I...
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Biochem Soc Trans (2005) 33 (4): 754–757.
Published: 01 August 2005
... electron-nuclear double resonance ETF electron transferring flavoprotein KIE kinetic isotope effect MAO monoamine oxidase TMADH trimethylamine dehydrogenase QSAR quantitative structure–activity relationship References 1 Rohlfs R.J. Hille R. J. Biol. Chem...
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Biochem Soc Trans (2005) 33 (4): 796–801.
Published: 01 August 2005
... 2005 © 2005 The Biochemical Society 2005 biodiversity cytochrome P450 electron transfer ferredoxin flavoprotein redox partner system Bacterial flavodoxins and ferredoxins are small redox proteins that participate in several key metabolic pathways. Ferredoxins are obligate one...
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Biochem Soc Trans (2003) 31 (6): 1095–1105.
Published: 01 December 2003
... electron transfer energy coupling Fourier-transform infrared spectroscopy (FTIR spectroscopy) mitochondria respiratory chain Abbreviation used: FTIR, Fourier-transform infrared. Keilin M em orialLecture The molecular machinery of Keilin s respiratory chain P.R. Rich1 Glynn Laboratory...
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Biochem Soc Trans (2003) 31 (3): 502–505.
Published: 01 June 2003
... binding of calmodulin (CaM) at elevated intracellular Ca 2+ levels to produce NO as part of a number of cell signalling pathways. CaM binds to the linker region between the two domains and activates the enzyme by inducing intramolecular electron transfer. Protein-engineering experiments have shown...
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Biochem Soc Trans (2003) 31 (3): 497–501.
Published: 01 June 2003
... and studies by site-directed mutagenesis have enabled detailed characterization of the mechanism of electron transfer using stopped-flow and equilibrium-perturbation methods, and redox potentiometry. These studies and the mechanism of electron transfer in CPR are reported herein. 1 To whom correspondence...
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Biochem Soc Trans (2002) 30 (4): 638–642.
Published: 01 August 2002
... bacterium Rhodovulum sulfidophilum is a heterodimeric c -type cytochrome that is involved in the oxidation of thiosulphate and sulphide. The recently solved crystal structure of the SoxAX complex represents the first structurally characterized example of a productive electron transfer complex between...
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Biochem Soc Trans (2002) 30 (4): 680–685.
Published: 01 August 2002
...J. Frazzon; J. R. Fick; D. R. Dean Iron-sulphur ([Fe-S]) clusters are simple inorganic prosthetic groups that are contained in a variety of proteins having functions related to electron transfer, gene regulation, environmental sensing and substrate activation. In spite of their simple structures...
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Biochem Soc Trans (2001) 29 (2): 139–147.
Published: 01 May 2001
...@ebi.ac.uk ) 23 11 2000 © 2001 Biochemical Society 2001 cytochrome b 5 electron transfer ferredoxin flavoprotein genome 3D, three-dimensional CPR, NADPH: cytochrome P450 reductase AdR, NADPH: adrenodoxin reductase Adx, adrenodoxin b5R, NADH: cytochrome b 5 reductase...
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Biochem Soc Trans (2000) 28 (4): 283–296.
Published: 01 August 2000
...V. Massey Since their discovery and chemical characterization in the 1930s, flavins have been recognized as being capable of both one- and two-electron transfer processes, and as playing a pivotal role in coupling the two-electron oxidation of most organic substrates to the one-electron transfers...