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Keywords: cofactors
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Biochem Soc Trans (2022) 50 (4): 1187–1196.
Published: 12 August 2022
..., during the biosynthesis of this cofactor. LarB uses a novel carboxylation mechanism involving the transient formation of a cysteinyl-pyridinium adduct. Depending on the source of the enzyme, LarEs either catalyze a sacrificial sulfur transfer from a cysteinyl side chain resulting in the formation...