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Keywords: radical S-adenosylmethionine (SAM)
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Biochem J (2014) 464 (1): e1–e3.
Published: 23 October 2014
... of the octanoyl chain. The challenging chemistry of this last step is performed by the radical S -adenosylmethionine (SAM) enzyme lipoyl synthase (LipA). In this issue of the Biochemical Journal , Harmer et al. report the first crystal structure of a lipoyl synthase and demonstrate that it contains two [4Fe–4S...